ATRP鍜孯AFT瑭﹀姂鏄彲鎺ц嚜鐢卞熀鑱氬悎瑭﹀姂涓噸瑕佺殑绲勬垚閮ㄥ垎锛屽畠鍊�?c猫)璇熷徎鑲垮辜鏉傝嫬願厗鎴忕；?y墨ng)涓�氶亷(gu貌)鎺у埗鑷敱鍩虹殑婵冨害锛岃(di脿o)绡�(ji茅)鍙嶆噳(y墨ng)閫熺巼銆佽仛鍚堢墿鍒嗗瓙绲�(ji茅)妲�(g貌u)鍜屽垎瀛愰噺鐨勫垎甯冮仈(d谩)鍒板皪(du矛)鑱氬悎鐗╁垎瀛愯鍓拰瑷�(sh猫)瑷�(j矛)鐨勭洰鐨�[1]銆�
鐧鹃潏濞佹彁渚涘绋�ATRP鍜�RAFT瑭﹀姂鍔╁姏鎮ㄧ殑绉戝(xu茅)鐮旂┒銆�
- 閬╃敤鍠珨鑼冨湇寤�
- 鍙嶆噳(y墨ng)姊濅欢婧拰
- 閬╃敤澶氱ó鑱氬悎鏂规硶
- 鏈夋晥鐨勬帶鍒惰仛鍚堢墿鍒嗗瓙绲�(ji茅)妲�(g貌u)浠ュ強鍒嗗瓙閲忓垎甯�
References
[1] Li X, Mastan E, Wang W J, et al. Progress in reactor engineering of controlled radical polymerization: a comprehensive review[J]. React.Chem.Eng, 2016, 1(1):23-59.
鈻� RAFT瑭﹀姂
|
鐢�(ch菐n)鍝佺法铏�(h脿o)
|
鑻辨枃鍚嶇ū(ch膿ng)
|
涓枃鍚嶇ū(ch膿ng)
|
CAS
|
|
252905
|
Tetramethylthiuram disulfide, 97%
|
浜岀～鍖栧洓鐢插熀绉嬭槶濮�
|
137-26-8
|
|
385880
|
S-(Thiobenzoyl)thioglycolic acid, 99%
|
S-(纭唬鑻敳?锛�?/span>)纭箼閰�
|
942-91-6
|
鈻� ATRP瑭﹀姂
|
鐢�(ch菐n)鍝佺法铏�(h脿o)
|
鑻辨枃鍚嶇ū(ch膿ng)
|
涓枃鍚嶇ū(ch膿ng)
|
CAS
|
|
134853
|
4,5-Bis(diphenylphosphino)-9,9-dimethylxanthene, 98%
|
4,5-闆欎簩鑻熀鑶�-9,9-浜岀敳鍩烘哀闆滆捊
|
161265-03-8
|
|
562561
|
Bromoacetonitrile, 97%
|
婧翠箼鑵�
|
590-17-0
|
|
382874
|
tert-Butyl α-bromoisobutyrate, 98%
|
α-婧翠唬鐣颁竵閰稿彅涓侀叝
|
23877-12-5
|
|
297002
|
Chloro(cyclopentadienyl)bis(triphenylphosphine)ruthenium(II), 99%
|
鐠�(hu谩n)鎴婁簩鐑洐(涓夎嫰鍩鸿啨)姘寲閲�(II)
|
32993-05-8
|
|
373381
|
(S)-(-)-2-Chloropropionic acidmethyl ester, 99%, ee: 98%
|
(S)-(-)-2-姘笝閰哥敳閰�
|
73246-45-4
|
|
162023
|
2-(Diphenylphosphino)benzoic acid, 98%
|
2-(浜岃嫰鍩鸿啨)鑻敳閰�
|
17261-28-8
|
|
200513
|
Diphenyl-2-pyridylphosphine, 97%
|
浜岃嫰鍩�-2-鍚″暥鍩鸿啨
|
37943-90-1
|
|
106648
|
Ethyl bromoacetate, 97%
|
婧翠唬涔欓吀涔欓叝
|
105-36-2
|
|
197651
|
Methyl bromoacetate, 98%
|
婧翠箼閰哥敳閰�
|
96-32-2
|
|
552440
|
Methyl 2-bromopropionate, 99%
|
2-婧翠笝閰哥敳閰�
|
5445-17-0
|
|
335651
|
Methyl chloroacetate, 99%
|
姘箼閰哥敳閰�
|
96-34-4
|
|
125128
|
Methyl 2-chloropropionate, 99%
|
2-姘笝閰哥敳閰�
|
17639-93-9
|
|
110246
|
Triphenylphosphine, 99%
|
涓夎嫰鍩鸿啨
|
603-35-0
|
|
409824
|
Tris(2-dimethylaminoethyl)amine, 99%
|
涓�(2-浜岀敳姘ㄥ熀涔欏熀)鑳�
|
33527-91-2
|
|
934562
|
Tris(2-pyridylmethyl)amine, 98%
|
涓�(2-鍚″暥鐢插熀)鑳�
|
16858-01-8
|
鈻� 鏇村鐢�(ch菐n)鍝佽珛(q菒ng)瑕�(ji脿n)锛�