3-姘�-1,2-涓欎簩閱�(3-MCPD)鏄竴椤炲湅(gu贸)闅涘叕瑾�(r猫n)鐨勯鍝佹薄鏌撶墿锛岄鍝佷腑鐨�3-MCPD涓昏渚�(l谩i)婧愪簬鑸囨鐗╄泲鐧界殑閰歌В銆傛摎(j霉)鍫�(b脿o)閬擄紝涓珮婵冨害鐨�3-MCPD鏈�(hu矛)閫犳垚鑵庤嚐鍜岀敓娈栧櫒瀹樼殑琛扮锛屾墍浠ュ湅(gu贸)闅涚檶鐧ョ爺绌舵(j墨)妲�(g貌u)(IARC)灏囧叾鍒楃偤2B椤炵殑鑷寸檶鐗╄唱(zh矛)[1]銆�3-MCPD鍥犲叾灏�(du矛)浜洪珨鍋ュ悍鐨勫嵄闅�(xi菐n)鎬�锛屽悇鍦�(gu贸)閮藉皪(du矛)姝ら鐗╄唱(zh矛)鍦ㄩ鍝佷腑鍚噺閫�(j矛n)琛屼簡瑕佹眰銆備緥濡傦細鎴戝湅(gu贸)銆�GB 2762-2012 椋熷搧瀹夊叏鍦�(gu贸)瀹舵(bi膩o)婧�(zh菙n) 椋熷搧涓薄鏌撶墿闄愰噺銆嬭(gu墨)瀹�锛�3-MCPD鍦ㄨ(di脿o)鍛冲搧绋殑鍚噺涓嶉珮浜�1 mg/kg銆�
MCPD閰篃鏄繎骞翠締(l谩i)鍦�(gu贸)鍏�(n猫i)澶栭鍝佸畨鍏ㄧ殑鐮旂┒鐔遍粸(di菐n)锛屽湅(gu贸)鍏�(n猫i)澶栭兘灏�(du矛)姝ら鐗╄唱(zh矛)鐨勬娓�(c猫)閮介��(j矛n)琛屼簡璜稿鍫�(b脿o)閬�[2]銆傜偤姝わ紝鐧鹃潏濞佹帹鍑篗CPD閰娓�(c猫)绯诲垪鐢�(ch菐n)鍝佸叏闈㈡湇鍕�(w霉)浜庨鍝佸畨鍏ㄦ娓�(c猫)鑸囨娓�(c猫)鏂规硶闁嬬櫦(f膩)銆�
References
[1] Lee B Q, Khor S M. 3鈥怌hloropropane鈥�1,2鈥恉iol (3鈥怣CPD) in Soy Sauce: A Review on the Formation, Reduction, and Detection of This Potential Carcinogen[J]. Comprehensive Reviews in Food Science and Food Safety, 2015, 14(1):48–66.
[2] Yu H W, Muhamad H, Abas F, et al. Effects of temperature and NaCl on the formation of 3-MCPD esters and glycidyl esters in refined, bleached and deodorized palm olein during deep-fat frying of potato chips[J]. Food Chemistry, 2016, 219:126–130.
鈻� GB/T 5009.191-2006 椋熷搧涓隘涓欓唶鍚噺鐨勬脯(c猫)瀹� 妯�(bi膩o)婧�(zh菙n)鍝�
妯�(bi膩o)婧�(zh菙n)鍝侊細
鍏�(n猫i)妯�(bi膩o)锛�
閰嶅瑭﹀姂锛�
|
鐢�(ch菐n)鍝佺法铏�(h脿o)
|
鑻辨枃鍚嶇ū
|
涓枃鍚嶇ū
|
CAS
|
|
100530
|
1-(Heptafluorobutyryl)imidazole, 97%
|
涓冩盁涓�?锛涱嫄婧�?/span>, 97%
|
32477-35-3
|
|
562397
|
p-Toluenesulfonic acid, 12 wt.% solution in acetic acid
|
灏�(du矛)鐢茶嫰纾洪吀, 12 wt.% 涔欓吀婧舵恫
|
104-15-4
|
鈻� 鍏朵粬MCPD閰皪(du矛)鐓у搧锛�
鍠叝锛�
|
鐢�(ch菐n)鍝佺法铏�(h脿o)
|
鐢�(ch菐n)鍝佸悕绋�
|
涓枃鍚嶇ū
|
绺
|
CAS
|
|
L467800
|
rac-3-Chloro-1,2-propanediol 1-linoleate
|
澶栨秷鏃�-3-姘�-1,2-涓欎簩閱�1-浜炴补閰搁叝
|
1-Li
|
74875-98-2
|
|
L467700
|
rac-3-Chloro-1,2-propanediol 1-linolenate
|
澶栨秷鏃�-3-姘�-1,2-涓欎簩閱�1-浜為夯閰搁叝
|
1-Ln
|
74875-99-3
|
|
O526800
|
rac-3-Chloro-1,2-propanediol 1-oleate
|
澶栨秷鏃�-3-姘�-1,2-涓欎簩閱�1-娌归吀閰�
|
1-OL
|
10311-82-7
|
|
P156500
|
rac-3-Chloro-1,2-propanediol 1-palmitate
|
澶栨秷鏃�-3-姘�-1,2-涓欎簩閱�1-妫曟珰閰搁叝
|
1-Pa
|
30557-04-1
|
|
S686525
|
rac-3-Chloro-1,2-propanediol 1-stearate
|
澶栨秷鏃�-3-姘�-1,2-涓欎簩閱�1-纭剛閰搁叝
|
1-St
|
22094-20-8
|
|
L184750
|
rac-1-Lauroyl-3-chloropropanediol
|
澶栨秷鏃�-1-鏈堟?锛�?/span>-3-姘笝浜岄唶
|
1-La
|
20542-96-5
|
|
M884750
|
rac-1-Myristoyl-3-chloropropanediol
|
澶栨秷鏃�-1-鑲夎眴钄�?锛�?/span>-3-姘笝浜岄唶
|
1-My
|
30557-03-0
|
闆欓叝锛�
|
鐢�(ch菐n)鍝佺法铏�(h脿o)
|
鐢�(ch菐n)鍝佸悕绋�
|
涓枃鍚嶇ū
|
绺
|
CAS
|
|
D460565
|
rac-3-Chloro-1,2-propanediol dilinolenate
|
澶栨秷鏃�-3-姘�-1,2-涓欎簩閱囦簩浜為夯閰搁叝
|
Ln-Ln
|
74875-97-1
|
|
D460595
|
rac-3-Chloro-1,2-propanediol dilinoleate
|
澶栨秷鏃�-3-姘�-1,2-涓欎簩閱囦簩浜炴补閰搁叝
|
Li-Li
|
74875-96-0
|
|
D482200
|
rac-3-Chloro-1,2-propanediol dioleate
|
澶栨秷鏃�-3-姘�-1,2-涓欎簩閱囦簩娌归吀閰�
|
OL-OL
|
69161-73-5
|
|
B515200
|
rac-3-Chloro-1,2-propanediol dipalmitate
|
澶栨秷鏃�-3-姘�-1,2-涓欎簩閱囦簩妫曟珰閰搁叝
|
Pa-Pa
|
51930-97-3
|
|
D493500
|
rac-3-Chloro-1,2-propanediol distearate
|
澶栨秷鏃�-3-姘�-1,2-涓欎簩閱囦簩纭剛閰搁叝
|
St-St
|
72468-92-9
|
|
L468400
|
rac-1-Linoleoyl-2-stearoyl-3-chloropropanediol
|
澶栨秷鏃�-1-浜炴补?锛�?/span>-2-纭剛?锛�?/span>-3-姘笝浜岄唶
|
Li-St
|
1246833-46-4
|
|
O530400
|
rac-1-Oleoyl-2-linolenoyl-3-chloropropanediol
|
澶栨秷鏃�-1-娌归叞鍩�-2-浜為夯?锛�?/span>-3-姘笝浜岄唶
|
OL-Ln
|
N/A
|
|
O530500
|
rac-1-Oleoyl-2-linoleoyl-3-chloropropanediol
|
澶栨秷鏃�-1-娌�?锛�?/span>-2-浜炴补?锛�?/span>-3-姘笝浜岄唶
|
OL-Li
|
1336935-03-5
|
|
O532900
|
rac-1-Oleoyl-2-stearoyl-3-chloropropanediol
|
澶栨秷鏃�-1-娌�?锛�?/span>-2-纭剛?锛�?/span>-3-姘笝浜岄唶
|
OL-St
|
1336935-05-7
|
|
P158950
|
rac-1-Palmitoyl-2-linoleoyl-3-chloropropanediol
|
澶栨秷鏃�-1-妫曟珰?锛�?/span>-2-浜炴补?锛�?/span>-3-姘笝浜岄唶
|
Pa-Li
|
1246833-87-3
|
|
P163500
|
rac-1-Palmitoyl-2-stearoyl-3-chloropropanediol
|
澶栨秷鏃�-1-妫曟珰?锛�?/span>-2-纭剛?锛�?/span>-3-姘笝浜岄唶
|
Pa-St
|
1185060-41-6
|
鍏朵粬鍏�(n猫i)妯�(bi膩o)鐗╋細
|
鐢�(ch菐n)鍝佺法铏�(h脿o)
|
鐢�(ch菐n)鍝佸悕绋�
|
涓枃鍚嶇ū
|
绺
|
|
D488223
|
rac-3-Chloro-1,2-propanediol dioleate-13C36
|
澶栨秷鏃�-3-姘�-1,2-涓欎簩閱囦簩娌归吀閰�-13C36
|
OL-OL-d5
|
|
L468402
|
rac-1-Linoleoyl-2-stearoyl-3-chloropropanediol-d5
|
澶栨秷鏃�-1-浜炴补?锛�?/span>-2-纭剛?锛�?/span>-3-姘笝浜岄唶-d5
|
Li-St-d5
|
|
O530502
|
rac-1-Oleoyl-2-linoleoyl-3-chloropropanediol-d5
|
澶栨秷鏃�-1-娌�?锛�?/span>-2-浜炴补?锛�?/span>-3-姘笝浜岄唶-d5
|
OL-Li-d5
|
|
O532902
|
rac-1-Oleoyl-2-stearoyl-3-chloropropanediol-d5
|
澶栨秷鏃�-1-娌归叞鍩�-2-纭剛?锛�?/span>-3-姘笝浜岄唶-d5
|
OL-St-d5
|
|
P158952
1246833-66-8
|
rac-1-Palmitoyl-2-linoleoyl-3-chloropropanediol-d5
|
澶栨秷鏃�-1-妫曟珰?锛�?/span>-2-浜炴补?锛�?/span>-3-姘笝浜岄唶-d5
|
Pa-Li-d5
|
鈻� 鐩搁棞(gu膩n)鐢�(ch菐n)鍝侊細