鍥虹浉寰悆?銆�?/span>SPME锛�鏄竴绋揩閫�銆佹搷浣滅啊鍠笖缍犺壊鐒℃憾鍔戠殑妯ｅ搧鍓嶈檿鐞嗘妧琛�(sh霉)銆傝┎鎶�琛�(sh霉)渚濇摎(j霉)鍚搁檮/鑴檮锛屽湪娌掓湁鏈夋(j墨)婧跺姂鍜屽京(f霉)闆滆ō(sh猫)鍌欑殑鎯呮硜涓�锛岀敤鍥虹浉寰悆鍙栬悆鍙栭牠锛堝張鍙�SPME鎺㈤嚌銆�SPME钀冨彇闋�锛夎悆鍙栧瘜闆嗗湪姘ｉ珨銆佹恫楂旀垨鍥洪珨妯ｅ搧涓殑鍖栧悎鐗�锛屾浛浠ｉ��(j矛n)妯ｉ嚌锛岄��(j矛n)琛屾埃鐩歌壊璀滈��(j矛n)妯�銆傝┎鏂规硶闈堟晱搴﹂珮锛屽彲瀵�(sh铆)鐝�(xi脿n)瓒呯棔閲忓垎鏋�锛岄仈(d谩)鍒扮磵鍏嬫瘡鍏嬬礆(j铆)鍒ョ殑妾㈡脯(c猫)銆�
鐧鹃潏濞佷綔鐐哄皥妤�(y猫)鍖栧(xu茅)鍝�銆佸剙鍣ㄨ�楁潗渚涙噳(y墨ng)鍟�锛屼緷鎵樼従(xi脿n)鏈夋(bi膩o)婧�(zh菙n)渚涙噳(y墨ng)鍩虹(ch菙)锛岄枊鐧�(f膩)鑷富鍝佺墝鐨勫浐鐩稿井钀冨彇鐢�(ch菐n)鍝�锛屾豢瓒崇棔閲忕墿璩�(zh矛)鐝�(xi脿n)鍫村彇妯ｏ紝鍙婂揩閫�銆佺稜鑹茬挵(hu谩n)淇濈殑妾㈡脯(c猫)鍒嗘瀽瑕佹眰銆�
鈻� 鐢�(ch菐n)鍝佺壒榛�(di菐n)
鈼� 閲嶅京(f霉)鎬уソ锛�
1. 鍠敮鎺㈤嚌閲嶅京(f霉)鎬ф娓�(c猫)瑭�(p铆ng)鍍�(ji脿)
鑷�涓诲搧鐗屾帰閲�鍠敮閲嶅京(f霉)鎬ф娓�(c猫)绲�(ji茅)鏋�RSD姣旈��(j矛n)鍙ｅ搧鐗屼綆1-2%
|
鍝佺墝
|
鐩(bi膩o)鍖栧悎鐗�
|
RSD锛�%锛�n=5
|
|
鑷富鍝佺墝
|
鐢茶嫰
|
3.08
|
|
閯颁簩鐢茶嫰
|
2.35
|
|
閫�(j矛n)鍙ｅ搧鐗�
|
鐢茶嫰
|
4.43
|
|
閯颁簩鐢茶嫰
|
4.24
|
2. 澶氭敮鎺㈤嚌骞宠鎬ф娓�(c猫)瑭�(p铆ng)娓�(c猫)
鑷富鍝佺墝鎺㈤嚌澶氭敮骞宠鎬ф娓�(c猫)绲�(ji茅)鏋�RSD姣旈��(j矛n)鍙ｅ搧鐗屼綆4-5%
|
鍝佺墝
|
鐩(bi膩o)鍖栧悎鐗�
|
RSD锛�%锛�
|
|
鑷富鍝佺墝
|
鐢茶嫰
|
3.65
|
|
閯颁簩鐢茶嫰
|
5.86
|
|
閫�(j矛n)鍙ｅ搧鐗�
|
鐢茶嫰
|
8.35
|
|
閯颁簩鐢茶嫰
|
8.58
|
鈼� 钀冨彇鏁堢巼楂�锛氳垏閫�(j矛n)鍙ｅ搧鐗岀浉鐣�(d膩ng)锛屾垨鐣ラ珮浜庨��(j矛n)鍙ｅ搧鐗�锛�
3. 椋熷搧棰�(f膿ng)鍛崇墿璩�(zh矛)妾㈡脯(c猫)灏�(du矛)姣�
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妾㈡脯(c猫)鏌愬搧鐗屽共绱呰憽钀勯厭鐨勯ⅷ(f膿ng)鍛崇墿璩�(zh矛)銆傜敱鍦栧彲鐭�锛岃嚜涓诲搧鐗屾帰閲濆嘲闈㈢⿳楂樹簬閫�(j矛n)鍙ｅ搧鐗屾帰閲�锛屼笖钀冨彇鍑虹殑鎴愬垎绋澶氫簬閫�(j矛n)鍙ｆ帰閲�銆傝嚜涓诲搧鐗屾帰閲濆皪(du矛)鐗瑰緛鐗╄唱(zh矛)鑻敳閱涚敘(ch菐n)鐢熶簡鍚搁檮骞舵鍑�锛岃�岄��(j矛n)鍙ｆ帰閲濇湭鑳芥鍑鸿嫰鐢查啗銆�
鈼� 鎬у児(ji脿)姣旈珮锛氭�ц兘鑸囬��(j矛n)鍙ｅ搧鐗岀浉鐣�(d膩ng)锛屼絾鍍�(ji脿)鏍兼洿瀵�(sh铆)鎯�锛�
鈼� 鑸囬��(j矛n)鍙ｅ搧鐗岀煶鑻辨潗璩�(zh矛)鐨勬帰閲濈浉姣旓紝鑷富鍝佺墝鐨勪笉閵归嫾鏉愯唱(zh矛)浣跨敤澹藉懡鏇撮暦锛�
鈼� 灏堟キ(y猫)鏈嶅嫏(w霉)锛氭彁渚涢伕鍨嬪強瀹氬埗鏈嶅嫏(w霉)銆�
鈻� 閬告搰鎸囧崡
|
妾㈡脯(c猫)妯ｅ搧椤炲瀷
|
鍙伕鎿囪悆鍙栭牠椤炲瀷
|
钀冨彇闋(gu墨)鏍�
|
|
闈炴サ鎬ф彯鐧�(f膩)鐗�(MW 60-275)
|
鑱氫簩鐢插熀纭呮哀鐑�(PDMS)
|
100 μm, 1 cm
|
|
闈炴サ鎬у崐鎻櫦(f膩)鐗�(MW 80-500)
|
鑱氫簩鐢插熀纭呮哀鐑�(PDMS)
|
30 μm, 1 cm
|
|
闈炴サ鎬ч珮鍒嗗瓙閲忓寲鍚堢墿(MW 125-600)
|
鑱氫簩鐢插熀纭呮哀鐑�(PDMS)
|
7 μm, 1 cm
|
|
姘ｉ珨鍜屼綆鍒嗗瓙閲忔贩鍚堢墿(MW 30-225)
|
娲绘�х偔/鑱氫簩鐢插熀纭呮哀鐑�(CAR/PDMS)
|
75 μm, 1 cm
85 μm, 1 cm
|
|
鎻櫦(f膩)鐗�, 鑳洪鍖栧悎鐗�, 纭濆熀鑺抽鏃忓寲鍚堢墿(MW 50-300)
|
鑱氫簩鐢插熀纭呮哀鐑�/鑱氫簩涔欑儻鍩鸿嫰(PDMS/DVB)
|
65 μm, 1 cm
|
|
鑺抽鍖栧悎鐗�(鎻櫦(f膩)鐗╁拰鍗婃彯鐧�(f膩)鐗� C3-C20 MW 40-275)
|
涓夊堡寰�(f霉)鍚�(DVB/CAR/PDMS)
|
50/30 μm, 1 cm
|
|
妤垫�у崐鎻櫦(f膩)鐗�(MW 80-300)
|
鑱氫笝鐑吀閰�(PA)
|
85 μm, 1 cm
|
|
閱囧拰妤垫�у寲鍚堢墿(MW 40-275)
|
鑱氫箼鐑唶(PEG)
|
60 μm, 1 cm
|
|
妤垫�х墿璩�(zh矛), 灏ゅ叾閱囬(MW 40-275)
|
鑱氫箼浜岄唶/浜屼箼鐑熀鑻�(CW/DVB)
|
65 μm, 1 cm
70 μm, 1 cm
|
.png)
鈻� 鐢�(ch菐n)鍝佸垪琛�
鈼� 鍥虹浉寰悆鍙栬悆鍙栭牠 (3鏀�/鐩�)
|
鐢�(ch菐n)鍝侀鍨�
|
鐢�(ch菐n)鍝佺法铏�(h脿o)
|
鐢�(ch菐n)鍝佽(gu墨)鏍�
|
浣跨敤椤炲瀷
|
椤忚壊
|
|
鑱氫簩鐢插熀纭呮哀鐑�(PDMS)
|
9117003
|
100 μm, 1 cm
|
鎵嬪嫊(d貌ng)
|
鐧借壊
|
|
962347
|
鑷嫊(d貌ng)
|
|
956410
|
30 μm, 1 cm
|
鎵嬪嫊(d貌ng)
|
鐧借壊榛戣姱
|
|
928911
|
鑷嫊(d貌ng)
|
|
964935
|
7 μm, 1 cm
|
鎵嬪嫊(d貌ng)
|
鐧借壊绱呰姱
|
|
949738
|
鑷嫊(d貌ng)
|
|
娲绘�х偔/鑱氫簩鐢插熀纭呮哀鐑�(CAR/PDMS)
|
9117004
|
75 μm, 1 cm
|
鎵嬪嫊(d貌ng)
|
榛戣壊
|
|
908595
|
鑷嫊(d貌ng)
|
|
953591
|
85 μm, 1 cm
|
鎵嬪嫊(d貌ng)
|
绮夎壊
|
|
925264
|
鑷嫊(d貌ng)
|
|
鑱氫簩鐢插熀纭呮哀鐑�/鑱氫簩涔欑儻鍩鸿嫰(PDMS/DVB)
|
9117005
|
65 μm, 1 cm
|
鎵嬪嫊(d貌ng)
|
榛冭壊
|
|
947194
|
鑷嫊(d貌ng)
|
|
涓夊堡寰�(f霉)鍚�(DVB/CAR/PDMS)
|
9117006
|
50/30 μm,
1 cm
|
鎵嬪嫊(d貌ng)
|
绱呰壊
|
|
916797
|
鑷嫊(d貌ng)
|
|
鑱氫笝鐑吀閰�(PA)
|
9117007
|
85 μm, 1 cm
|
鎵嬪嫊(d貌ng)
|
缍犺壊
|
|
939015
|
鑷嫊(d貌ng)
|
|
鑱氫箼鐑唶(PEG)
|
9117008
|
60 μm, 1 cm
|
鎵嬪嫊(d貌ng)
|
绱壊
|
|
909296
|
鑷嫊(d貌ng)
|
|
鑱氫箼浜岄唶/浜屼箼鐑熀鑻�(CW/DVB)
|
9117009
|
65 μm, 1 cm
|
鎵嬪嫊(d貌ng)
|
钘�(l谩n)鑹�
|
|
966664
|
鑷嫊(d貌ng)
|
|
912942
|
70 μm, 1 cm
|
鎵嬪嫊(d貌ng)
|
钘�(l谩n)鑹查粦鑺�
|
|
953342
|
鑷嫊(d貌ng)
|
鈼� 鍥虹浉寰悆鍙栭厤浠�鐢�(ch菐n)鍝�
|
鐢�(ch菐n)鍝佺法铏�(h脿o)
|
鐢�(ch菐n)鍝佸悕绋�
|
鑻辨枃鍚嶇ū
|
鍖呰瑕�(gu墨)鏍硷紙鍊�(g猫)锛�
|
|
1079548
|
鍥虹浉寰悆鍙栨墜鏌�
|
SPME handle
|
1EA
|
|
9116970
|
鍥虹浉寰悆鍙栧皫(d菐o)鍚戝櫒
|
SPME guider
|
1EA
|
|
9116971
|
鍥虹浉寰悆鍙栫幓鐠冩敧鎷屽瓙
|
SPME stir bar
|
6EA
|
鈻� 鍏稿瀷鎳�(y墨ng)鐢ㄧず渚�锛岄粸(di菐n)鎿婃煡鐪�
鈻� 鍏朵粬鐢�(ch菐n)鍝�