鑳哄寲鍙嶆噳(y墨ng)涔熺ū姘ㄨВ鍙嶆噳(y墨ng)锛屾槸鎸囧湪鏈夋(j墨)鍖栧悎鐗╁垎瀛愪腑寮曚汉姘ㄥ熀鐢熸垚鑳洪鍖栧悎鐗╃殑鍙嶆噳(y墨ng)銆傝繎骞翠締锛屼竴浜涙柊鍨嬭兒鍖栬│鍔戝洜鍏跺弽鎳�(y墨ng)姊濅欢婧拰銆佸弽鎳�(y墨ng)鏀剁巼楂樼殑鐗归粸(di菐n)鑰岃寤ｆ硾鎳�(y墨ng)鐢�銆備緥濡傞洐锛堝彅涓佹哀缇板熀锛夎兒锛�51779-32-9锛夈�佷簩鐢查叞鑳洪垑楣斤紙18197-26-7锛夌瓑銆傜櫨闈堝▉鎻愪緵鐨勫绋柊鍨嬭兒鍖栬│鍔戯紝鐢�(ch菐n)鍝佺磾搴﹂珮锛屽弽鎳�(y墨ng)鏀剁巼楂�锛屽湅鍏�(n猫i)鐝�(xi脿n)璨ㄥ厖瓒筹紝鍙揩閫熸豢瓒冲(sh铆)椹�(y脿n)鑸囩敓鐢�(ch菐n)闇�姹�銆�
浜炴皑鍩轰簩缇ч吀锛堝彅涓佸熀鐢插熀锛夐叝锛�66389-76-2锛夋槸鍒跺倷鍠繚璀�(h霉)姘ㄧ殑楂樻晥鑳哄寲瑭﹀姂[1]锛屽畠鍙互鑸囬沟浠ｇ兎鍙嶆噳(y墨ng)鐢熸垚浜炶兒鍖栧悎鐗�2锛屼簽鑳哄寲鍚堢墿2 鐢ㄥ牽鎴栭吀铏曠悊锛屽彲鍒嗗垾寰楀埌N-Boc淇濊(h霉)鑳哄寲鍚堢墿3 鎴朜-鐢叉哀鍩洪叞鑳哄寲鍚堢墿4 锛屼笖浜炴皑鍩轰簩缇ч吀锛堝彅涓佸熀鐢插熀锛夐叝鍙綔鐐洪吀鎬цΚ鏍歌│鍔戝弮鑸嘙itsunobu鍙嶆噳(y墨ng)锛屽皣缇ュ熀杞�(zhu菐n)鍖栨垚姘ㄥ熀銆�
姝ゅ锛屽偓鍖栧姂閰嶉珨鐨勭櫦(f膩)灞曟摯(ku貌)灞曚簡搴曠墿鐨勯仼鐢ㄨ寖鍦�锛屾彁楂樹簡鍙嶆噳(y墨ng)鐨勯伕鎿囨��锛岃繎骞翠締锛孭d鍌寲鑺宠兒鍖栧唬娉涚敤浜庡悎鎴愯姵鑳洪鍖栧悎鐗�[2]銆�
鈻� 鐢�(ch菐n)鍝佸垪琛�
|
鐢�(ch菐n)鍝佺法铏�
|
鑻辨枃鍚嶇ū
|
涓枃鍚嶇ū
|
CAS
|
鍖呰
|
|
|
4-Amino-4H-1,2,4-triazole, 99%
|
4-姘ㄥ熀-4H-1,2,4-涓夋爱鍞�
|
|
5 g
25 g
100 g
|
|
|
O-Methylhydroxylamine hydrochloride, 99%
|
鐢叉哀鑳洪菇閰搁菇
|
|
5 g
25 g
100 g
|
|
|
Potassium phthalimide, 99%
|
閯拌嫰浜岀敳閰颁簽鑳哄寲閴�
|
|
100 g
500 g
|
|
|
N,O-Dimethylhydroxylamine hydrochloride, 99%
|
N,O-浜岀敳鍩虹茎鑳洪菇閰搁菇
|
|
5 g
25 g
100 g
|
|
|
Diphenylphosphoryl azide, 98%
|
鐤婃爱纾烽吀浜岃嫰閰�
|
|
25 g
100 g
|
|
|
Sodium diformamide, 98%
|
浜岀敳閰拌兒閳夐菇
|
|
5 g
25 g
|
|
|
Hydroxylamine hydrochloride, 99%
|
缇ヨ兒楣介吀楣�
|
|
100 g
250 g
|
|
|
Di-tert-butyl iminodicarboxylate, 97%
|
浜炶兒浜岀晶閰镐簩鍙斾竵閰�
|
|
1 g
5 g
25 g
|
|
|
Hydroxylamine sulfate, 99%
|
纭吀缇ヨ兒
|
|
5 g
100 g
1 kg
|
|
|
Hydroxylamine-O-sulfonic acid, 97%
|
缇ヨ兒-O-纾洪吀
|
|
25 g
100 g
1 kg
|
References:
[1] U.Ragnarsson,L.Grehn,Acc.Chem.Res.,1991,24,285.
[2] Eun Jeong Yoo, Sandy Ma, Tian-Sheng Mei, J. Am. Chem. Soc., 2011, 133 (20), 7652-7655.