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       鍣佸攽鍟夋槸鍚湁N鍜�O鍘熷瓙鐨勪簲鍏冮洔鐠�(hu谩n)鍖栧悎鐗�锛屽叾涓�N鍘熷瓙鍙綔鐐轰緵闆诲瓙鍘熷瓙鑳借垏Cu銆�Mg銆�Ni銆�Pd銆�Zn銆�Rh绛夊绋噾灞洟瀛愰厤浣�銆傝繎骞翠締锛屾墜鎬�鍣佸攽鍟夐厤楂�鐨勫悎鎴�鍙婂叾鎳�(y墨ng)鐢ㄧ爺绌舵槸鏈夋(j墨)鍚堟垚鍖栧(xu茅)闋�(l菒ng)鍩熸瘮杓冩椿韬嶇殑瑾查涔嬩竴銆�

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       鐧鹃潏濞佸彲浠ユ彁渚汿OX & SaBOX銆�PyBox, Box, Phox绛夐厤楂旂ó椤烇紝鍝佽唱(zh矛)鍎�(y艒u)鐣�锛屾兜钃嬩簡鍣佸攽鍟夐厤楂旀噳(y墨ng)鐢ㄧ殑鎵�鏈夐鍒ワ紝鍏呭垎婊胯冻鎮ㄧ殑瀵�(sh铆)椹�(y脿n)闇�姹�銆�

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鐠�(hu谩n)涓欑兎鐨刐3+3]涓嶅皪绋辩挵(hu谩n)鍖栧弽鎳�(y墨ng) & 涓嶅皪绋遍枊鐠�(hu谩n)鍙嶆噳(y墨ng)
Tang, Y. et al., Angew. Chem.Int. Ed. 2013, 52, 1452
Tang, Y. et al., J. Am. Chem.Soc. 2012, 134, 9066
 
閰嶉珨1579639鐨勬洿澶氭噳(y墨ng)鐢紝璜嬭涓嬪垪鏂囩嵒(xi脿n)
a) Tang, Y. et al., Angew. Chem. Int. Ed. 2010. 49, 4463
b) Tang, Y. et al., Tetrahedron2012, 68, 5042
c) Jason S, et al., Org. Lett.2011, 13, 2004
d) Jason S, et al., Synthesis, 2012, 44, 686
Tang, Y. et al., J. Am. Chem. Soc. 2013, 135, 7851.
 
鐑兇鐨勪笉灏嶇ū鐠�(hu谩n)涓欑兎鍖栧弽鎳�(y墨ng)

Tang, Y. et al., Angew. Chem. Int. Ed. 2012, 51, 8838
Tang, Y. et al., Angew. Chem. Int. Ed. 2012, 51, 11620
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鐢�(ch菐n)鍝佸悕绋�
CAS
(3aS,3a'S,3a''S,8aR,8a'R,8a''R)-2,2',2''-(Propane-1,2,2-triyl)tris(8,8a-dihydro-3aH-indeno[1,2-d]oxazole), 99%
(3aS,3a'S,3a''S,8aR,8a'R,8a''R)-2,2',2''-(涓欑兎-1,2,2-涓夊熀)涓�(8,8a-浜屾矮-3aH-鑼氬苟[1,2-d]鍣佸攽)
(4S,4'S)-2,2'-(1-Phenylpropane-2,2-diyl)bis(4-phenyl-4,5-dihydrooxazole), 99%
(4S,4'S)-2,2'-(1-鑻笝鐑�-2,2-浜屽熀)闆�(4-鑻熀-4,5-浜屾矮鍣佸攽)
(4S,4'S)-2,2'-(1,3-Bis(4-(tert-butyl)phenyl)propane-2,2-diyl)bis(4-phenyl-4,5-dihydrooxazole), 99%
(4S,4'S)-2,2'-(1,3-闆�(4-(鍙斾竵鍩�)鑻熀)涓欑兎-2,2-浜屽熀)闆�(4-鑻熀-4,5-浜屾矮鍣佸攽)
(3aS,3a'S,8aR,8a'R)-2,2'-(1,3-bis(3,5-di-tert-butylphenyl)propane-2,2-diyl)bis(8,8a-dihydro-3aH-indeno[1,2-d]oxazole), 99%
(3aS,3a'S,8aR,8a'R)-2,2'-(1,3-闆�(3,5-浜屽彅涓佸熀鑻熀)闆�(8,8a-浜屾矮-3aH-鑼氬苟[1,2-d]鍣佸攽)

 鈻� PyBOX 

鍚″挴灏嶉潧绱呯殑鍔犳垚鍙嶆噳(y墨ng)
Org. Lett., 2011,13 (21), 5754-5757
 
鐤婃爱-鐐旂兇鐠�(hu谩n)鍔犳垚鍙嶆噳(y墨ng)
J.Am.Chem.Soc., 2013, 135 (30), 10994-10997

鐢�(ch菐n)鍝佺法铏�
鐢�(ch菐n)鍝佸悕绋�
CAS
2,6-Bis[(4S)-(-)-isopropyl-2-oxazolin-2-yl]pyridine, 99%
2,6-闆橻(4S)-(-)-鐣颁笝鍩�-2-鍣佸攽鍟�-2-鍩篯鍚″暥
2,6-Bis[(4R)-(+)-isopropyl-2-oxazolin-2-yl]pyridine, 98%
2,6-闆橻(4R)-(+)-鐣颁笝鍩�-2-鍣佸攽鍟�-2-鍩篯鍚″暥
2,6-Bis[(4R)-4-phenyl-2-oxazolinyl]pyridine, 98%
2,6-闆橻(4R)-4-鑻熀-2-鍣佸攽鍟夊熀]鍚″暥
2,6-Bis[(4S)-4-phenyl-2-oxazolinyl]pyridine, 98%
2,6-闆橻(4S)-4-鑻熀-2-鍣佸攽鍟夊熀]鍚″暥
2,6-Bis[(3aR,8aS)-(+)-8H-indeno[1,2-d]oxazolin-2-yl)pyridine, 95%
2,6-闆橻(3aR,8aS)-(+)-8H-鑼氬苟[1,2-d]鍣佸攽鍟�-2-鍩篯鍚″暥
2,6-Bis[(3aS,8aR)-(-)-8H-indeno[1,2-d]oxazolin-2-yl)pyridine, 95%
2,6-闆橻(3aS,8aR)-(-)-8H-鑼氬苟[1,2-d]鍣佸攽鍟�-2-鍩篯鍚″暥
2,6-Bis[(4S)-4,5-dihydro-4-(1-methylethyl)-5,5-diphenyl-2-oxazolyl]-pyridine, 98%
2,6-闆橻(4S)-4,5-浜屾矮-4-(1-鐣颁笝鍩�)-5,5-浜岃嫰鍩�-2-鍣佸攽鍩篯鍚″暥
2,6-Bis[(4R)-4,5-dihydro-4-(1-methylethyl)-5,5-diphenyl-2-oxazolyl]-pyridine, 98%
2,6-闆橻(4R)-4,5-浜屾矮-4-(1-鐣颁笝鍩�)-5,5-浜岃嫰鍩�-2-鍣佸攽鍩篯鍚″暥

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缇板熀鐨�α-鑺冲熀鍖栧弽鎳�(y墨ng)

 

J.Am.Chem.Soc., 2011, 133 (35), 13782-13785
鐢�(ch菐n)鍝佺法铏�
鐢�(ch菐n)鍝佸悕绋�
CAS
2,2′-Isopropylidenebis[(4S)-4-tert-butyl-2-oxazoline], 98%
2,2'-鐣颁簽涓欏熀闆橻(4S)-4-鍙斾竵鍩�-2-鍣佸攽鍟塢
(+)-2,2′-Isopropylidenebis[(4R)-4-benzyl-2-oxazoline], 98%
(+)-2,2'-鐣颁簽涓欏熀闆橻(4R)-4-鑺愬熀-2-鍣佸攽鍟塢
(-)-2,2′-Isopropylidenebis[(4S)-4-phenyl-2-oxazoline], 97%
(-)-2,2'-鐣颁簽涓欏熀闆橻(4S)-4-鑻熀-2-鍣佸攽鍟塢
(+)-2,2′-Isopropylidenebis[(4R)-4-phenyl-2-oxazoline], 97%
(+)-2,2'-鐣颁簽涓欏熀闆橻(4R)-4-鑻熀-2鍣佸攽鍟塢
[3aR-[2(3′aR*,8′aS*),3′aβ,8′aβ]]-(+)-2,2′-Methylenebis[3a,8a-dihydro-8H-indeno[1,2-d]oxazole], 98%
[3aR-[2(3'aR*,8'aS*),3'aβ,8'aβ]]-(+)-2,2'--浜炵敳鍩洪洐[3a,8a-浜屾矮-8H-鑼氬苟[1,2-d]鍣佸攽]
[3aS-[2(3′aR*,8′aS*),3′aα,8′aα]]-(-)-2,2′-Methylenebis[3a,8a-dihydro-8H-indeno[1,2-d]oxazole], 98%
[3aS-[2(3'aR*,8'aS*),3'aα,8'aα]]-(-)-2,2'-浜炵敳鍩洪洐[3a,8a-浜屾矮-8H-鑼氬苟[1,2-d]鍣佸攽]
(4S,4′S)-2,2′-(Cyclopentane-1,1-diyl)-bis(4-isopropyl-4,5-dihydrooxazole), 95%
(4S,4'S)-2,2'-(鐠�(hu谩n)鎴婄兎-1,1-浜屽熀)-闆�(4-鐣颁笝鍩�-4,5-浜屾矮鍣佸攽)

 鈻� PhOX

α-鍙栦唬鐨勮嫰涔欑儻鍩鸿鐢熺墿鐨勭〖姘寲鍙嶆噳(y墨ng)
 
Chem. Commun., 2011, 47, 298-300
鐢�(ch菐n)鍝佺法铏�
鐢�(ch菐n)鍝佸悕绋�
CAS
(S)-4-tert-Butyl-2-[2-(diphenylphosphino)phenyl]-2-oxazoline, 97%
(S)-4-鍙斾竵鍩�-2-[2-(浜岃嫰鍩鸿啨鍩�)鑻熀]-2-鍣佸攽鍟�
(R)-(+)-2-[2-(Diphenylphosphino)phenyl]-4-isopropyl-2-oxazoline, 98%
(R)-(+)-2-[2-(浜岃嫰鍩鸿啨)鑻熀]-4-鐣颁笝鍩�-2-鍣佸攽鍟�
(S)-(-)-2-[2-(Diphenylphosphino)phenyl]-4-isopropyl-2-oxazoline, 97%
(S)-(-)-2-[2-浜岃嫰鍩鸿啨]鑻熀]-4-鐣颁笝鍩�-2-鍣佸攽鍟�
(R)-(-)--2-[2-(Diphenylphosphino)phenyl]-4-phenyl-2-oxazoline, 97%
(R)-(-)-2-[2-(浜岃嫰鍩鸿啨)鑻熀]-4-鑻熀-2-鍣佸攽鍟�
(S)-(+)-2-[2-(Diphenylphosphino)phenyl]-4-phenyl-2-oxazoline, 97%
(S)-(+)-2-[2-(浜岃嫰鍩鸿啨)鑻熀]-4-鑻熀-2-鍣佸攽鍟�
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